Product ID:SHIELD TITE WET SURFACE COATING
MSDS Date:08/14/1991
FSC:5610
NIIN:00N037107
MSDS Number: BQTRB

PIONEER/RANDUSTRIAL

4529 INDUSTRIAL PARKWAY
CLEVELAND, OH 44135
US

Emergency Phone: 216-671-5500

Info Phone: 216-641-7500

Preparer: ANDRY SCHOLEM

Cage: 52190

RANDUSTRIAL

CLEVELAND, OH 44135 US

Telephone: 216-641-7500

Cage: 52190

RESP IS SHALLOW. GET MED ATTN. DO NOT GIVE ANYTHING

RTECS: 9999999ZZ

IF AVAIL. REMOVE ALL CONTAM CLTHG TO PVNT FURTHER

RTECS: 9999999ZZ

W/SOAP & WATER. LEATHER SHOES THAT HAVE BEEN

RTECS: 9999999ZZ

LIQ TO SALVAGE TANK. REMAINING LIQ MAY BE TAKEN

RTECS: 9999999ZZ

ABSORB LIQ ON

RTECS: 9999999ZZ

& TRANSFER TO A HOOD.

RTECS: 9999999ZZ

LIQ INCIN I/A/W APPLIC REGS. CONTAM ABSORB

RTECS: 9999999ZZ

SMOKING. SOAP & WATER SHOWER SHLD BE TAKEN @ END

RTECS: 9999999ZZ

COAL TAR PITCH VOLATILES (BENZENE SOLUBLE FRACTION),

CAS: 65996-93-2

RTECS: GF8655000

OSHA PEL 0.2 MG/M3

ACGIH TLV: 0.2 MG/M3

COAL TAR

CAS: 8007-45-2

RTECS: GF8600000

Fraction By Weight: 40-70%

PETROLEUM HYDROCARBON

CAS: 68553-00-4

Fraction By Weight: 10-30%

PALYGORSITE; (MAGNESIUM)

CAS: 12174-11-7

RTECS: AT6400000

Fraction By Weight: 4.5-15%

SILICA, CRYSTALLINE - QUARTZ

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: <1.65%

OSHA PEL SEE TABLE Z3

ACGIH TLV: 0.1 MG/M3 RDUST;9293

4.2-13.2.

CAS: 1317-65-3

RTECS: EV9580000

Fraction By Weight: SEE ING

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

MAGNESIUM CARBONATE; (MAGNESITE)

CAS: 546-93-0

RTECS: OM2470000

Fraction By Weight: 0.5-1.9%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

5.2-7.15.

CAS: 91-20-3

RTECS: QJ0525000

Fraction By Weight: SEE ING

OSHA PEL 10 PPM;15 PPM STEL

ACGIH TLV: 10 PPM;15 PPM STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

0.65-0.98

CAS: 92-52-4

RTECS: DU8050000

Fraction By Weight: SEE ING

OSHA PEL 0.2 PPM

ACGIH TLV: 0.2 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

100-42-4)

CAS: 100-42-5

RTECS: WL3675000

Fraction By Weight: 0.13%

OSHA PEL 100 PPM

ACGIH TLV: S,50PPM/100STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

0.32-0.65

CAS: 108-95-2

RTECS: SJ3325000

Fraction By Weight: SEE ING

OSHA PEL 5 PPM, S

ACGIH TLV: 5 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

0.65-0.98

CAS: 120-12-7

RTECS: CA9350000

Fraction By Weight: SEE ING

OSHA PEL 0.2 MG/M3

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

0.32-0.65

CAS: 1300-71-6

RTECS: ZE5425000

Fraction By Weight: SEE ING

OSHA PEL 100 PPM;150 PPM STEL

ACGIH TLV: 100 PPM;150 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CRESOL, ALL ISOMERS; (CRESYLIC ACID) (SARA III).

CAS: 1319-77-3

RTECS: GO5950000

Fraction By Weight: SEE ING

OSHA PEL 5 PPM, S

ACGIH TLV: 5 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

DERM & W/POOR HYG PRACTS, TO SKIN CANCER. PRLNG

RTECS: 9999999ZZ

LIVER, KIDNEYS, SPLEEN & NERVOUS SYSTEM.

RTECS: 9999999ZZ

FOR @ LST 15 MINS, OCCAS LIFTING EYELIDS. GET MED

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:COAL TAR VAPS ARE IRRIT TO SKIN,
EYES & RESP TRACT. DIRECT SKIN CONT &/OR HIGH VAP CONCS MAY CAUSE
BURN/ITCH, CHANGES IN PIGMENTATION & SKIN ERUPTIONS. DIRECT EYE
CONT MAY CAUSE INFLAMM, DISCOMF ORT, CONJ & POSS ABRASION OF
CORNEA. INGEN ACUTE ORAL TOX IS CONSIDERED TO BE MOD, BUT INGEST IS
NOT (EFTS OF OVEREXP)
Explanation of Carcinogenicity:COAL TAR PITCH:GRP 1(IARC). SILICA
CRYSTALLINE - QUARTZ:GRP 2A(IARC), ANTIC TO BE A CARCIN(NTP).
STYRENE:GRP 2B(IARC).
Effects of Overexposure:HLTH HAZ:LIKELY TO BE PRIMARY RTE OF EXPOS.
SYMPS OF SYSTEMIC POIS AFTER INGEST MAY INCL SALIVATION, VOMIT,
RESP DFCLTIES, DIZZ, HDCH, LOSS OF PUPILLARY REFLEXES, CYANOSIS,
HYPORTHERMIA & MILD CONVLS. ASPIR OF MATL INTO LUNGS MAY CAUSE
CHEM PNEUM WHICH MAY LEAD TO PERM & IRREVERSIBLE LUNG DMG & EVEN BE
FATAL. (SUPDAT)
Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN
DISORDERS MAY BE AT INCREASED RISK FROM OVEREXPOSURE. EXPOSURE TO
VAPORS MAY AGGRAVATE PRE-EXISTING LUNG OR BRONCHIAL CONDITIONS.

First Aid:INHAL:REMOVE FROM EXPOS AREA TO FRESH AIR IMMED. IF BRTHG HAS
STOPPED, GIVE ARTF RESP. KEEP AFFECTED PERS WARM & @ REST. GIVE
OXYGEN IF RESP IS SHALLOW. GET MED ATTN. SKIN:WASH EXPOS AREA TWICE
W/WATE RLESS HAND CLEANER, SOAP & WATER/MILD DETERGENT. DO NOT USE
SOLVS AS THEY MAY PROMOTE ABSORPTION OF MATL. GET MED ATTN IF
IRRIT/PAIN PERSISTS AFTER WASHING. EYES:RINSE IMMED W/LG AMT OF
WATER (ING 17)

Flash Point Method:PMCC
Flash Point:>150F,>66C
Extinguishing Media:CARBON DIOXIDE, WATER FOG, DRY CHEMICALS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. WATER/FOAM MAY CAUSE FROTHING WHICH CAN BE VIOLENT & POSS
ENDANGER LIFE OF FIREFIGHTER, ESP IF (SUPDAT)
Unusual Fire/Explosion Hazard:NEVER USE WELDING/CUTTING TORCH ON/NEAR
DRUM (EVEN EMPTY). PROD CAN IGNITE EXPLOSIVELY. SENSITIVITY TO
STATIC DISCHARGE.

Spill Release Procedures:LG SPILLS:ELIM ALL IGNIT SOURCES (FLARES,
FLAMES INCL PILOT LIGHTS, ELEC SPKS). PERS NOT WEARING PROT EQUIP
SHLD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN
COMPLETED. STOP SPILL @ SOURCE, DIKE AREA OF SPILL TO PVNT
SPREADING, PUMP(ING 21)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:PROT CNTNRS AGAINST PHYSICAL DMG.
OUTSIDE/DETACHED STOR IS PREF. INSIDE STOR SHLLD BE IN STD FLAMM
LIQS STOR ROOM/CABINET IF MATL IS FLAMM/COMBUST.
Other Precautions:WEAR PROT EQUIP WHEN PERFORMING MAINT ON CONTAM
EQUIP. PERS SHLD AVOID INHAL OF VAPS & PERSONAL CONT W/CMPD. DO NOT
GET IN EYES/SKIN. WHEN HNDLG, CMPD MUST BE KEPT AWAY FROM ALL
SOURCES OF IGNIT. HAVE NIOSH/MSHA APPRVD RESP AVAIL.

Respiratory Protection:PROVIDE NIOSH/MSHA APPROVED HALF-FACE PIECE
FILTER OR CHEMICAL CARTRIDGE RESPIRATOR OR FULL FACE CONTINUOUS
CONTROL FLOW, POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR AS
NECESSARY FOR PROTECTION FROM COA L TAR PITCH VOLATILES.
Ventilation:MAINTAIN VENTILATION AS NECESSARY FOR PROTECTION FROM COAL
TAR PITCH VOLATILES.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEM WORK GOG W/FULL LGTH FCSHLD .
Other Protective Equipment:EMERGENCY EYE WASH & DELUGE SHOWER . BOOTS,
IMPERVIOUS COATS.
Work Hygienic Practices:CONT LENSES SHLD NOT BE WORN. DO NOT SMOKE/EAT
IN AREAS WHERE MATL IS HNDLD. WASH HANDS THORO BEFORE EATING/ (ING
25)
Supplemental Safety and Health
FIRE FIGHT:SPRAYED INTO CNTNRS OF HOT, BURNING LIQ. NORMAL FIRE
FIGHTERS PROCS MAY BE USED. EFTS OF OVEREXP:IRRIT TO BRONCH SYS,
EYES, SKIN. SENSIT:POSS TO SKIN RASHES. CHRONIC:HIGH VAP
CONCS/CHRONIC EXPOS TO LEVELS ABOVE TLV MAY LEAD TO SYSTEMIC SYMPS
(SEE ACUTE ORAL TOX SYMPS). PRLNG/RPTD CONT MAY LEAD TO (ING 15)

HCC:V4
Boiling Pt:B.P. Text:>302F,>150C
Vapor Pres:5 @ 20C
Vapor Density:<1
Spec Gravity:1.2
pH:NEUT
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK SEMI-LIQUID W/STRONG COAL TAR ODOR.
Percent Volatiles by Volume:<5

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CO, CO*2 & UNIDENTIFIED ORGANIC
COMPOUNDS.

Waste Disposal Methods:SM SPILL:WEAR PROT EQUIP AS NEC. ALLOW VOLAT
PORTION TO EVAP UNDER HOOD. ALLOW SUFFICIENT TIME FOR VAPS TO
COMPLETELY CLEAR HOOD DUCT WORK. DISP OF REMAINING MATL I/A/W
APPLIC LOC, STATE & FED REGS. L G SPILL:WEAR PROT EQUIP AS NEC.
DESTROYBY(ING 24)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.